Micellar solubilization
Process of incorporating the solubilizate into or onto micelles
Micellar solubilization (solubilization) is the process of incorporating the solubilizate (the component that undergoes solubilization) into or onto micelles. Solubilization may occur in a system consisting of a solvent, an association colloid (a colloid that forms micelles), and at least one other solubilizate.
01Usage of the term
Solubilization is distinct from dissolution because the resulting fluid is a colloidal dispersion involving an association colloid. This suspension is distinct from a true solution, and the amount of the solubilizate in the micellar system can be different (often higher) than the regular solubility of the solubilizate in the solvent.
In non-chemical literature and in everyday language, the term "solubilization" is sometimes used in a broader meaning as "to bring to a solution or (non-sedimenting) suspension" by any means, e.g., leaching by a reaction with an acid.
02Application
Micellar solubilization is widely utilized, e.g. in laundry washing using detergents, in the pharmaceutical industry, for formulations of poorly soluble drugs in solution form, and in cleanup of oil spills using dispersants.
03Mechanism
Literature distinguishes two major mechanisms of solubilization process of oil by surfactant micelles, affecting the kinetics of solubilization: surface reaction, i.e., by transient adsorption of micelles at the water-oil interface, and bulk reaction, whereby the surfactant micelles capture dissolved oil molecules.
Sources and credits
This article is adapted from the Wikipedia article “Micellar solubilization”, written by its contributors and licensed under CC BY-SA 4.0. Fathomly has changed the layout, removed citation markers, navigation and maintenance notices, and adjusted punctuation. This adapted version is shared under the same license. For references, see the original article.
Images, from Wikimedia Commons:
- Encapsulating process.jpg by Andreas Dries, Public domain
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