Pinene

α-Pinene and β-pinene are both produced from geranyl pyrophosphate, via cyclisation of linaloyl pyrophosphate followed by loss of a proton from the carbocation equivalent. Researchers at the Georgia Institute of Technology and the Joint BioEnergy Institute have been able to synthetically produce pinene with a bacterium.

Alpha-pinene is the most widely encountered terpenoid in nature and is highly repellent to insects.

Alpha-pinene appears in conifers and numerous other plants. Pinene is a major component of the essential oils of Sideritis spp. (ironwort) and Salvia spp. (sage). Cannabis also contains alpha-pinene and beta-pinene, as well as the dried finished flowers known as marijuana. Resin from Pistacia terebinthus (commonly known as terebinth or turpentine tree) is rich in pinene. Pine nuts produced by pine trees contain pinene.

Makrut lime fruit peel contains an essential oil comparable to lime fruit peel oil; its main components are limonene and β-pinene. Essential oils of other citrus fruits like oranges and lemons also include racemic mixtures of alpha- and beta-pinene. Oils of herbs like rosemary and basil also contain racemic mixtures of pinene.

The racemic mixture of the two forms of pinene is found in some oils like eucalyptus oil.

α-Pinene

Selective oxidation of α-pinene occurs at the allylic position to give verbenone, along with pinene oxide, as well as verbenol and its hydroperoxide.

Pinene's chiral bicyclic nature and availability makes it an attractive chiral starting material for complex syntheses. For example, pinene was explored by Paul Wender as a starting material for his total synthesis of taxol.

α-Pinene can be converted to camphor by way of isobornyl acetate. Hydrogenation of pinene gives pinane, precursor to a useful pinanehydroperoxide. The hydroboration of α-pinene has been extensively examined. With borane-dimethylsulfide, two equivalents of α-pinene react to give (diisopinocampheyl)borane. Reaction with 9-BBN gives the reagent called alpine borane. This sterically crowded chiral trialkylborane can stereoselectively reduce aldehydes in what is known as the Midland Alpine borane reduction.

β-pinene

β-pinene can be converted to α-pinene in the presence of strong bases, or pyrolysed to produce myrcene at 400 °C.

Pinenes, especially α, are the primary constituents of turpentine, a nature-derived solvent and fuel.

The use of pinene as a biofuel in spark ignition engines has been explored. Pinene dimers have been shown to have heating values comparable to the jet fuel JP-10.

α-Pinene is shown to have anti-inflammatory and memory-boosting properties.